Several preconditions must be satisfied before a Rb-Sr date can be considered as representing the time of emplacement or formation of a rock. One of the major drawbacks and, conversely, the most important use of utilizing Rb and Sr to derive a radiometric date is their relative mobility, especially in hydrothermal fluids.
Rb and Sr are relatively mobile alkaline elements and as such are relatively easily moved around by the hot, often carbonated hydrothermal fluids present during metamorphism or magmatism. Conversely, these fluids may metasomatically alter a rock, introducing new Rb and Sr into the rock generally during potassic alteration or calcic albitisation alteration. Rb-Sr can then be used on the altered mineralogy to date the time of this alteration, but not the date at which the rock formed.
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Thus, assigning age significance to a result requires studying the metasomatic and thermal history of the rock, any metamorphic events, and any evidence of fluid movement. A Rb-Sr date which is at variance with other geochronometers may not be useless, it may be providing data on an event which is not representing the age of formation of the rock. The Rb-Sr dating method has been used extensively in dating terrestrial and lunar rocks, and meteorites.
The dates indicate the true age of the minerals only if the rocks have not been subsequently altered. Although this is a potential source of error for terrestrial rocks, it is irrelevant for lunar rocks and meteorites, as there are no chemical weathering reactions in those environments. The application of Sr isotope stratigraphy is generally limited to carbonate samples for which the Sr seawater curve is well defined.
This is well known for the Cenozoic time-scale but, due to poorer preservation of carbonate sequences in the Mesozoic and earlier, it is not completely understood for older sequences. In older sequences diagenetic alteration combined with greater uncertainties in estimating absolute ages due to lack of overlap between other geochronometers for example U—Th leads to greater uncertainties in the exact shape of the Sr isotope seawater curve.
Note that this is not always true. If a magma cools quickly on the surface of the Earth, some of the Ar may be trapped. If this happens, then the date obtained will be older than the date at which the magma erupted. For example lavas dated by K-Ar that are historic in age, usually show 1 to 2 my old ages due to trapped Ar.
Such trapped Ar is not problematical when the age of the rock is in hundreds of millions of years. The dating equation used for K-Ar is: Some of the problems associated with K-Ar dating are Excess argon. This is only a problem when dating very young rocks or in dating whole rocks instead of mineral separates.
Minerals should not contain any excess Ar because Ar should not enter the crystal structure of a mineral when it crystallizes. Thus, it always better to date minerals that have high K contents, such as sanidine or biotite. If these are not present, Plagioclase or hornblende. If none of these are present, then the only alternative is to date whole rocks. Some 40 Ar could be absorbed onto the sample surface. This can be corrected for.
Most minerals will lose Ar on heating above o C - thus metamorphism can cause a loss of Ar or a partial loss of Ar which will reset the atomic clock. If only partial loss of Ar occurs then the age determined will be in between the age of crystallization and the age of metamorphism.
http://police-risk-management.com/order/reviews/tygan-cellulari-ricondizionati-iphone.php If complete loss of Ar occurs during metamorphism, then the date is that of the metamorphic event. The problem is that there is no way of knowing whether or not partial or complete loss of Ar has occurred. Examples of questions on this material that could be asked on an exam. Prior to the best and most accepted age of the Earth was that proposed by Lord Kelvin based on the amount of time necessary for the Earth to cool to its present temperature from a completely liquid state.
Principles of Radiometric Dating Radioactive decay is described in terms of the probability that a constituent particle of the nucleus of an atom will escape through the potential Energy barrier which bonds them to the nucleus. Thus, if we start out with 1 gram of the parent isotope, after the passage of 1 half-life there will be 0. Some examples of isotope systems used to date geologic materials.
To see how we actually use this information to date rocks, consider the following: To account for this, we first note that there is an isotope of Sr, 86 Sr, that is: If we divide equation 4 through by the amount of 86 Sr, then we get: Note also that equation 5 has the form of a linear equation, i. How can we use this? In nature, however, each mineral in the rock is likely to have a different amount of 87 Rb.
Thus, once the rock has cooled to the point where diffusion of elements does not occur, the 87 Rb in each mineral will decay to 87 Sr, and each mineral will have a different 87 Rb and 87 Sr after passage of time. The Concordia curve can be calculated by defining the following: The discordia is often interpreted by extrapolating both ends to intersect the Concordia.
Pb leakage is the most likely cause of discordant dates, since Pb will be occupying a site in the crystal that has suffered radiation damage as a result of U decay. U would have been stable in the crystallographic site, but the site is now occupied by by Pb. An event like metamorphism could heat the crystal to the point where Pb will become mobile. Another possible scenario involves U leakage, again possibly as a result of a metamorphic event. U leakage would cause discordant points to plot above the cocordia. The Age of the Earth A minimum age of the Earth can be obtained from the oldest known rocks on the Earth.
So far, the oldest rock found is a tonalitic Gneiss metamorphic rock rock from the Northwest Territories, Canada, with an age of 3. This gives us only a minimum age of the Earth.
Is it likely that we will find a rock formed on the Earth that will give us the true age of the Earth? Rubidium has two isotopes 85 Rb When a mineral crystallizes, it will usually incorporate both rubidium and strontium ions and the ratio of Rb to Sr will vary depending on the mineral involved. Using these proportions it is possible to identify the amount of radiogenic 87 Sr present.
Originally the above proportions were assumed, but today it is more usual to plot 87 Sr: When using the 87 Rb: